Interaction of gasoline volatile organic compounds with three different soils. Part II – Laboratory simulation of decontamination
DOI:
https://doi.org/10.14195/2184-8394_113_5Keywords:
Contaminated soils, Laboratory tests, Mitigation/remediation, BTEX – Benzene, Toluene, Ethylbenzene and XylenesAbstract
This work results from a laboratory simulation study of the ventilation decontamination process of diverse soils, which were reconstituted in reactors designed and constructed at specific purpose, after they had been doped with BTEX. The soil specimens were reconstituted with different characteristics, two spe ci - mens for each kind of soil. By using that laboratory simulation, the interactions among BTEX (Benzene, To - lue ne, Ethylbenzene and Xilenes) contaminants in gas phase and soil aqueous and solid phases were studied for the diverse soils. The soil conditions that might allow higher or smaller reversibility of intervenient pro - ces ses were also evaluated. The results obtained concluding that the influence of soil nature and their geo - technical conditions are not so clear, how was foreseen, being obvious the importance of water content, that was maintained constant during all tests, by saturation of percolant air flux.
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References
Atlas, R.M. (1981). Microbial degradation of petroleum hydrocarbons: An environmental Pers pec - ti ve. Microbiological Reviews, vol.45, nº1, pp. 180-209.
Bayard, R. (1997). Étude de l’absorption/désorption de polluants organiques dans le sols. Approche méthodologique et application au pentachlorophenol et aux hydrocarbures aro ma ti - ques polycycliques. These présenteé devant L’ Institute National des Sciences Apliquées de Lyon pour obtenir de grade de docteur.
Calvet, R. (1989). Adsorption of organic chemicals in soils. Environmental Health Perspectives, vol.83, pp. 145-177.
Chiou, C.T.; Shoup, T.D. (1985). Soil sorption of organic vapors and effects of humidity on sorptive mechanisms and capacity. Environmental Sciences and Technology, vol.19, nº12, pp. 1196- 1200.
Christensen, J.S.; Elton, J. (1996). Soil and groundwater pollution from BTEX. Groundwater Pollution Primer, CE 4594; Civil Engineering Department, Virginia Tech..
Corapcioglu, M.Y.; Baehr, A.L. (1987). A compositional multiphase model for groundwater contamination by petroleum products. Part I – theoretical considerations. Water Resources Research, vol.23, nº1, pp. 191-200.
Farrel, J.; Reinhard, M. (1994). Desorption of halogenated organics from model solids, sediments, and soil under unsaturated conditions. Part II – Model Development. Environ. Sci. Technol., vol.28, nº1, pp. 63-72.
Fetter, C.W. (1993). Contaminant hydrology. Macmillan Publ. Co., New York.
Giles, C.H.; MacEwan, T.H.; Nakhwa, S.N.; Smith, D. (1960). Studies in adsorption. Part XI. A system of classification of solution adsorption isotherms and its use in diagnosis and adsorptive mechanism and measurements of specific surface area of solids. Chemical Society Journal, vol.3, pp. 3973-3993.
Jorge, C. (2001). Contaminação/Descontaminação de Solos com Gasolina – Influência das Carac - te rísticas dos Solos. Dissertação elaborada para a obtenção do grau de Doutor em Ciên cias de Engenharia pela Faculdade de Engenharia da Universidade do Porto.
Jorge, C; C.R. Moura; M.L. Lopes; A. Gomes-Coelho (2008). Interacção de compostos orgânicos voláteis da gasolina com três tipos de solos. Parte I – Desenvolvimento do estudo de retenção. Geotecnia, Revista da Sociedade Portuguesa de Geotecnia, nº. 113, pp. 55-83.
Karickhoff, S.W.; Morris, K.R. (1985) – Sorption dynamics of hydrophobic pollutants in sediment suspensions. Environ. Toxicol. Chem., vol.4, pp. 469-479.
Karickhoff, S.W. (1984) – Organic pollutant sorption in aquatic systems. Journal of Hydrology, ASCE, vol.110, nº 6, pp. 707-735.
Pennell, K.D.; Rhue, R.D.; Rao, P.S.C.; Johnson, C.T. (1992) – Vapor-phase sorption of p-xylene and water on soils and clay minerals. Environmental Sciences and Technologies, vol.26, nº4, pp. 756-762.
Peterson, M.S.; Lion, L.W.; Shoemaker, C.A. (1998). Influence of vapor-phase sorption and diffusion on the fate of trichloroethylene in an unsaturated aquifer system. Environmental Scien ces and Technologies, vol.22, nº5, pp. 571-578.
Riser-Roberts, E. (1998). Remediation of petroleum contaminated soils: biological, physical and chemical processes. Lewis Publishers.
Scheidegger, A.M.; Sparks, D.L. (1996). A critical assessment of sorption-desorption mechanisms at the soil mineral/water interface. Soil Science, vol.161, nº12, pp. 813-831.
Vilkner, V.L.; Parnas, R.S. (1986). Analysis of volatile hydrocarbons losses from quoesiescent water solutions. Water Resources Research, vol.22, nº5, pp. 812-818.
Williamson, D.G.; Loehr, R.C.; Kimura, Y. (1998). Release of chemicals from contaminated soils. Journal of Soil Contamination, vol.7, nº 5, pp. 543-558.
Wilson, D.J.; Clarke, A.N. (1994). Soil vapor stripping. Hazardous waste site soil remediation, theory and application of innovative technologies, D.J. Wilson e A.N. Clarke (eds), pp. 171- 243. Marcel Dekker, Inc., New York.
Yaron, B.; Calvet, R.; Prost, R. (1996). Soil pollution. Processes and dynamics. Springer, Berlin, Germany.